Since I'm not a fan of cold showers, I wanted to just buy a new water heater since this is ten years old, but I figure, in the spirit of DIY home improvement, why not just replace the faulty component and have some spare change left over. Coincidentally, when the plumber was here a few weeks earlier installing gas line, he too had a bit of difficulty getting the piezo to ignite the pilot. I then returned to redo the process, but then the piezo igniter was not producing a spark. The windproof design insures reliable lighting even under the most demanding conditions. So, I turned off the gas and let it air out for 10 minutes. The piezoelectric effect is very useful within many applications that involve the production and detection of sound, generation of high voltages, electronic frequency generation, microbalances, and ultra fine focusing of optical assemblies. The rugged metal case of The Eagle makes this the perfect lighter for the outdoorsmen. 1 I did get the pilot to re-light (saw the pilot light through the window), but I was not sure that I did it correctly (not sure why). This video will show how to teardown the Scorch torch and how to replace the piezo igniter when it no longer works. After the work was complete, I turned on the gas at the main and initiated the process to re-light the gas water heater pilot. I was doing some work on my residential gas lines which required turning off the gas at the main.
0 Comments
The difference in energy levels between 4s and 3d is small enough for the next two electrons to enter the 4s, because the electron-electron repulsion they feel if they enter 3d is enough to knock them into the 4s. So, with scandium, the first electron after completing the previous noble gas configuration goes into 3d. So, we have 3d and 4s co-filling rather than filling independently. However, because the 3d orbitals are smaller and more closely packed than the 4s, the electron-electron repulsion that occurs in the 3d subshell is enough to make it possible for 1 or 2 electrons to have a lower energy by occupying the 4s. In scandium and the other d block members of period 4, the 3d is lower in energy than the 4s. How much of a difference, and which subshell is lower in energy, varies by element. The 4s and 3d subshells have nearly the same energy level. I have assumed that the configuration that follows the rules is the ground state, since that is what is usually taught in general chemistry. Note: Nickel has two electron configurations that are commonly encountered over which there is a dispute amongst chemists as to which should be considered the ground state. There is a simple chart that makes learning the filling order easy. He did not know that La is an exception to the rule. Note: in one of his videos, Sal does the configuration of La, but he gets it wrong. However, it is unlikely you would be asked to know these in a general chemistry course. Thus, the actual configuration of the Pd is 4d¹⁰ (the 5s is empty).Īll the other exceptions are in the f block and just have to be learned on a case-by-case basis. Both of these electrons are instead in the outermost d subshell. In Pd (palladium) the outermost s subshell, predicted to have 2 electrons, is actually empty. In the following elements, there is 1 electron, not the predicted 2, in the outermost s subshell, the "missing" electron is instead located in the outermost d subshell: So, rather than going through the far more difficult to understand rules that do correctly predict the electron configurations for all elements, it is easier just to learn the elements that this simplified method doesn't work correctly for. There are similar irregularities in the filling of 5s and 4d as well as some other pairs of subshells. For example, the 4s and 3d have nearly the same energy level and so, in a way that varies according to which element it is, either of the two subshells could be the first to fill and there is no certainty that one will be completely filled before the other actually starts filling. The actual filling order is more complicated. This pattern will give you the correct configuration for all but about 19 elements. There are no known elements that, in their ground state, have electrons in a subshell beyond 7p. What you do is you start assigning electrons to the subshells using the following pattern (you completely fill up one subshell before moving onto the next higher) and you keep going until the total number of electrons assigned is equal to the atomic number:ġs, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p However, in the simplified version of these rules that is understandable to a general chemistry student, there are about 19 elements that are exceptions. Given the atomic number, there is a set of rules that allow you to determine the electron configuration. Without that, you cannot determine the electron configuration. You must know the atomic number of the element. One consequence of this independence was that the Shell logo used in the U.S. This was due in part to complex legal reasons as Royal Dutch Shell feared that there could be onerous liability problems if a closer control of Shell Oil's affairs was exercised by the "parent company". ĭespite the acquisition, however, Shell Oil remained a fairly independent business. However, in 1984, Royal Dutch Shell made a bid to purchase those shares of Shell Oil Company it did not own (around 30%) and despite some opposition from some minority shareholders which led to a court case, Shell completed the buyout for a sum of $5.7 billion. Limited direct involvement from the main office in The Hague, Netherlands, and having its stock "Shell Oil" traded on the New York Stock Exchange were factors. Until the mid-1980s Shell's business in the United States was substantially independent. It is listed in the National Register of Historic Places. The Shell Oil Company Warehouse, built in 1925 and located at 425 S. They are also the Official Fuel of the Indianapolis Motor Speedway Relationship with Shell plc In 2023 Shell USA (North American division of Shell plc) became the Official Fuel of the NTT Ind圜ar Series they will supply 100% Ethanol-sourced fuel. Shell fuel previously included the RU2000 and SU2000 lines (later there was a SU2000E) but they have been superseded by the V-Power line. The Shell Martinez Refinery in Martinez, California, the first Shell refinery in the United States, supplied Shell and Texaco stations in the West and Midwest until its sale to PBF Energy in 2020. Shell products include oils, fuels, and car services as well as exploration, production, and refining of petroleum products. However, Shell is currently divesting its interest in Motiva. Shell Oil Company was a 50/50 partner with the Saudi Arabian government-owned oil company Saudi Aramco in Motiva Enterprises, a refining and marketing joint venture which owns and operates three oil refineries on the Gulf Coast of the United States. At its gas stations Shell provides diesel fuel, fuel and LPG. which also serve as Shell's most visible public presence, and comes closest to serving all 50 states, lacking a presence only in Montana. Shell is the market leader through approximately 14,000 Shell-branded fuel stations in the U.S. The Shell Oil Company's former Natural Gas, and energy divisions are now Shell Energy North America, a closely integrated, but a distinctive entity that runs across North America and is headquartered out of Houston, Texas. This has come as a result of Royal Dutch Shell breaking off its Natural Gas and power businesses into a new segment named Integrated Gas. In recent years The Shell Oil Company's Midstream, and Downstream, in particular, have become limited to petroleum, and chemical products. In the year 2016, Shell Nederland Raffinaderij BV (Shell Pernis) said that it has started a new aromatics unit at the large Pernis refinery in Rotterdam, Netherlands. In 2002, Shell began converting these Texaco stations to the Shell brand, a process that was to be completed by June 2004 and was called "the largest retail re-branding initiative in American business history". Īfter Texaco merged with Chevron in 2001, Shell purchased Texaco's shares in the joint ventures. The other, known as Motiva Enterprises, combined the Eastern and Gulf Coast operations of Shell Oil and Star Enterprise, itself a joint venture between Saudi Aramco and Texaco. One combined their Midwestern and Western operations and was known as Equilon. In 1997, Shell and Texaco entered into two refining/marketing joint ventures. Shell USA, including its consolidated companies and its share in equity companies, is one of America's largest oil and natural gas producers, natural gas marketers, fuel marketers and petrochemical manufacturers. Approximately 18,000 Shell employees are based in the U.S. (formerly Shell Oil Company, Inc.) is the United States-based wholly owned subsidiary of Shell plc, a UK-based transnational corporation " oil major" which is amongst the largest oil companies in the world. Organometallic Thermochemistry Database:Ī description of the organometallic thermochemistry database.In-depth explanation of gas phase ion data availableĪ description of the primary source of thermochemical data Guide to this site and the data available from it. A Guide to the NIST Chemistry WebBook: A.Results from experiments involving flow over cylinders. Species by building up a chemical formula in Hill order.Ī collection of spray combustion data from experiments conducted High accuracy data for a select group of fluids.Įstimates of gas phase thermodynamic properties based Thermophysical Properties of Fluid Systems:.NIST reserves the right to charge for access to this database in the future. Liebman Miscellaneous data entry and editing Pamela J. Zhang,Īnn Marie Martin, Nimit Patel, Abbie Tran, Campbell 3-D Structures created by Karl K. Johnson IARPA / PNNL Solid Phase IR Spectra Timothy J. IARPA / PNNL Liquid Phase IR Spectra Tanya L. Lafferty Evaluated Infrared Reference Spectra Coblentz Society, Inc. Wallace director Quantitative Infrared Database Pamela M. Leskin Thermodynamics Source Database compiled by Thermodynamics Research Center, NIST Boulder Laboratories,Ĭhris Muzny director Names, 2-D Structures, Retention Indexes, Mass and IR Spectra data compiled by NIST Mass Spectrometry Data Center, McLinden UV/Visible Spectra compiled by Victor Talrose, Eugeny B. Stein Henry's Law Constants compiled by Rolf Sander Thermophysical Properties of Fluid Systems Eric W. Louis Boiling Point data compiled by Robert L. Literature of Chemistry), University of Missouri – St. Liebman, Students of Chem 202 (Introduction to the Chickos Heat of Fusion data compiled by James S. Martinho Simões Heat of Sublimation data compiled by James S. Johnson, III) Organometallic Thermochemical data compiled by José A. Jacox Vibrational Frequency data compiled by Takehiko Shimanouchi Constants of Diatomic Molecules compiled by Klaus P. Lias Vibrational and Electronic Energy Level data compiled by Marilyn E. Dunbar Proton Affinity data compiled and evaluated by Edward P. Lias Metal Ion Clustering Data compiled by Robert C. Bartmess Thermochemistry of Cluster Ion data compiled by Michael N. Lias Negative Ion Energetics data compiled by John E. Kafafi Ionization Energy data evaluated by Sharon G. Hearing Ionization Energetics (IE, AE) data compiled by Sharon G. Entropy and Heat Capacity of Organic Compounds compiled by Glushko Thermocenter, Moscow Condensed Phase Heat Capacity data compiled by Eugene S. Neutral Thermochemical data compiled by Hussein Y. The director, John Badham (" WarGames"), possibly believes that his aerial sequences are so compelling that the rest of the plot can be hurried through. Logic, that tiresome specter at the feast of fantasy, here raises its skeletal hand and asks a few questions, like (1) Why does the computer whiz need to be in the building to crack the computers? Hasn't he ever heard of a modem? And (2) wouldn't people in central Washington be likely to notice skydivers parachuting into a semi driving down a major street? "Drop Zone" shrugs off those and all other questions as it hurtles to a conclusion. They jump to the top of a federal building, use the computer nerd to hack into secret files, and then escape by parachuting into the bed of a moving semi-trailer truck on the streets below. And he realizes that Busey and his gang have not only survived their jump from the 747, but now plan another audacious scheme. allegedly the only night of the year when skydivers can violate the capitol's protected air space. Soon Jessie points Pete to the legendary 4th of July jump in Washington, D.C. He's aided in his search by Jessie Crossman ( Yancy Butler), who runs her own skydiving school, makes her own rules, and treats Nessip to a dangerous thrill on his first ride, by pushing him out of the plane without a parachute. ("Give me your gun and your badge," his superior says not the first time we've heard that in a movie.) The marshal decides to sniff around for suspects in the world of championship-level skydiving, and soon picks up a promising trail. Everyone tells him it's impossible to jump out of a 747 at 38,000 feet and live (and I am prepared to believe this), but he's offended, because his brother (Malcolm-Jamal Warner) has been accused of endangering the airplane, and he is even a suspect himself. The stunt is so audaciously planned and executed that it doesn't look like an escape bid, and the missing persons are all presumed dead - by everyone except Nessip (an anagram for Snipes, although why they overlooked Pissen is beyond me). But first they need to spring computer mastermind Earl Leedy ( Michael Jeter) from prison, and that leads to a scene in a 747 at 38,000 feet where the bad guys snatch Leedy from his federal escort and parachute with him through a gaping hole in the side of the plane. marshal, and Gary Busey as Ty Moncrief, the leader of a renegade gang of skydivers who have an audacious scheme to sell the secrets of the DEA to druglords. The movie stars Wesley Snipes as Pete Nessip, a hard-charging U.S. Alternatively, make a pair of sculptural earrings the subtle focus of your outfit by sticking to a monochromatic color scheme, then tying your hair back to let them shine quietly.Īhead, 21 pairs of minimalist earrings to shop now-and wear forever. Looking for an overall minimalist look with a bold finish? Try pairing an ear full of mixed-metal huggies with a white button-down and oversized, wide-leg trousers. We love the unique patterns they’re able to create with clay, as well as the eye-popping color combinations of each piece. The brand molds tropical ferns and flowers into life through clay, which makes their exotic designs so interesting. While some designers have made a name for themselves thanks to their minimalist aesthetic (think: J.Hannah, Jenny Bird, and Bagatiba), others like Agmes, Pattaraphan, and Lizzie Fortunato offer a range of styles that vacillate between bold and insouciant. Simple Stud Earrings, Tiny Studs, Dainty Studs Earrings, 925 Sterling Silver Studs, Gift For Her, Minimalist Studs Earrings (PAIR), KYCE47 (182) 15.97 FREE shipping Gold Abalone Circle Dangle Earrings, Abalone Ear Jewelry, Minimalist Drop Earrings, Fun, Cute, Geometric (11) 5. To say that Hola, Said Lola is inspired by nature is an understatement. Even more, understated hoops, elegant structural drop earrings, and unfussy studs are so timeless in their own right that they might as well serve as part of your seasonal capsule wardrobe. Of course, the best minimalist earrings aren’t necessarily plain: They can be delicate, sophisticated, and serve as the finishing touch on any look. Chandelier earrings had a pretty solid run-but sometimes, when your outfit is already doing the talking, simple, uncomplicated jewelry is all you need. The loaded salt potatoes are just one of the distinct food items on the Bull and Bear’s menu, which also includes “rough road pasta,” a unique take on Central New York’s chicken riggie dish (pasta tossed in smoky tomato cream sauce, andouille sausage, onion and grilled chicken breast). Dinosaur’s menu may reflect barbecue influences from across the United States, but over the course of three decades, this signature Central New York restaurant has found a way to fuse those flavors together and create an experience that is uniquely Syracuse. But its Syracuse location – where bikers and office workers dine side by side, and where pictures of musicians who have jammed at the live music bar there like ZZ Top line the walls –cannot be beat for its atmosphere. Diners can top their barbecue with their choice of nine different sauces and rubs served at the restaurant and sold online, from its signature “Sensuous Slathering BBQ Sauce” to wango tango habanero, Creole honey mustard and Devil’s Duel Hot Sauce.ĭinosaur has since expanded to seven restaurants across the Northeast. Dinosaur uses four different cheeses in its macaroni and cheese, hand cuts its potatoes for its French fries and even serves fried green tomatoes, creole deviled eggs, a “big ass pork plate” and a “drunken spicy shrimp boil” cooked in beer. Louis ribs to a Memphis pulled pork topped with coleslaw and a crispy Cajun catfish entree. The menu at Dinosaur reflects Stage’s travels, from St. So, he worked with a series of vendors at the Boston Fish Pier when opening Doug’s to truck in haddock, cod, scallops, clams and other seafood on ice from the Atlantic Ocean to Skaneateles five days a week. Clark struggled to find fish dinners outside of the Friday fish fries common during Lent at Central New York churches and restaurants. We hope our good food and fair prices will please you,” another states.Īnd then there’s the red awning in front of the restaurant that’s been there since its opening in 1982, that simply states in large letters “GOOD FOOD.”ĭoug’s has been serving fresh fish dinners since the days when founder Doug Clark brought his family to this scenic village along 16-mile Skaneateles Lake for day trips and identified the need for a casual restaurant that served quality food and cold beer. “Three things most restaurants do: Take reservations. “If you have a reservation, you are in the wrong place,” one sign reads. With an expansive outdoor seating area, Sweet Treats ice cream shop next door and Onondaga Lake across the street, Heid’s is the quintessential Syracuse summer hangout. The mustard – now also sold by the bottle in the ordering line – is just one of many storied traditions at Heid’s, which began in the 1880s when the Heid family first opened a butcher shop in Liverpool followed by a hot dog stand. The true way to eat a Heid’s dog is with just its housemade spicy brown mustard, which until the 1990s was the only condiment available until customers began to clamor for ketchup and other toppings. They’re served on a New England style roll split at the top rather than on the side – a rarity at hot dog stands further west in Buffalo. Choose from a Hofmann’s red frank or a white coney, also known as a “snappy griller:” a particularly juicy hot dog flavored with spices that give it an extra kick. Heid’s features hot dogs from Hofmann Sausage Company, an iconic Syracuse brand that originated in the 1870s. It’s only at the end of the line that customers make the final ask for hot dogs there’s always some simmering on the flat top grill just behind the cashier. After purchase, you may go to the iTunes Settings to manage your subscription and turn the automatic renewal off. Once the subscription is confirmed, your iTunes account will be charged according to the plan you chose. The subscription will automatically renew on expiry unless the automatic renewal is turned off at least 24 hours before the expiry of the current subscription period. The fees for the Fotor Pro plan are paid following purchase confirmation. Ad-free! The Fotor Pro subscription fee is charged monthly or yearly. Join Fotor Pro, unlock all advanced photo-editing tools, photo effects, design templates, backgrounds, and more professional design resources, which are updated weekly. Stickers, frames, fonts, backgrounds, mosaic, stock photos, massive elements resources, to enhance your creation. You can also customize the design templates, adjust the text, etc. Various creative design templates with themes covering daily life, work, ads, business trade, and other occasions. At the same time, it adjusts the photo perspective, such as distortion, and stretching, thus achieving more creativity. It freely supports photo composition, enabling cropping, rotating, and flipping. More than 100 professional photo effects and stylish filters, such as real analog film, retro, fresh, black and white, and more classical effects, suitable for various scenes with a variety of aesthetic styles. In addition to the basic photo-editing tools, it offers more advanced photo-editing features, such as Curve, HSL, Color balance, Dahaze, Denoise, which meet all requirements. They couldn’t even tell me how to cancel it.īased on a special model algorithm and machine learning technique, it turn photos into works like those painted by Van Gogh, Monet, Picasso, other masters and also trendy NFT styles such as cryptopunk. I just never had such an annoying support person who obviously didn’t know what they were taking about and then confused me, claimed I owed money, then when I lashed back acted like they didn’t know what I was talking about. Extremely wishy-washy and all I can say is, at least the support, that this app is poorly managed, regardless of if it has good features. They then contradicted themselves and all of a sudden didn’t know what I was talking about. They freaked me out about having to pay something, and then when I told them I didn’t sign up to pay and didn’t receive any notifications, they avoided answering my direct question. First off there was no payment, they do nothing to prompt you of this “payment” for a FREE TRIAL, and every time I messaged support, the person I talked to wouldn’t help me cancel my account, and kept making excuses. So I contacted support and they told me I can only cancel on a desktop - and then said that I’d be charged for ending the trial. I went to cancel my trial but there was no obvious way to do it on the app. I do find however that there is a bit of compression for finer, smaller text, and so for graphic creation I give the edge to Canva, another free app. If you’d like a free, usable app that doesn’t limit too many of your creative choices, this is a good one, especially for simple collage creation. But I mostly don’t use the app for graphic creation, just collages, so it doesn’t affect me one way or another. There isn’t much in the way of ads or in-app purchases, although they are available, like stickers. There’s layouts that are pay to use, but I’ve gotten by with the essential free ones, and no complaints here. I’ve used the web app as well, and it’s a lot more in-depth and allows more fine tuning, such as enlarging and positioning exactly. Can zoom, increase/decrease borders, choose different grid layouts, change aspect ratio (square, wide, narrow) for different projects. I mostly make photo collages and it’s simple enough for that. I like what’s available for use for the free users. Have been using the Fotor mobile app for over a year now. I’ve paid for Premium from September 2019 to September 20, 2020. I deleted and then downloaded and installed Fotor again moments ago. I also hope I get a response from their Support Team.Sincerely,M. Couldn’t they, at least, write us on their App if they are experiencing difficulties? It would make for good customer relations.I hope I get to use Fotor. I had thought that with the Pandemic that has crippled the entire World, they would likely have very few people working. I’ve written their Support but have not received a response. The thing is I have not been able to use it. Trouble of some kind since start of Subscription. I presently have a yearly subscription that is good until September 20, 2020. It was always one of my favorites.Now, at the present moment in time, it is failing me. I was a subscriber since Fotor came into existence on both my desktop and iPad. If you use commercial brands of Aspen or Cypress bedding please be careful as they may contain a high amount of dust or other contaminants that can be harmful. It is recommended to stick to well-known substrates that are designed for use with reptiles. Zoo Med Aspen Snake Bedding is another possible substrate for Red Tail Boas and many enjoy using it. We particularly like the Zoo Med Forest Floor Cypress Bedding or Zoo Med Eco Earth for use with Red Tail Boas. Since like most snakes, Red Tail Boas are escape artists, a secure screen top is absolutely critical to keep your snake from escaping the enclosure. There is no such thing as a cage too big for a Red Tail Boa so larger is always better especially if you provide some climbing room since Red Tail Boas are very happy to climb and hang out off of the ground. Adults will end up needing an enclosure that is either 6' x 2' x 2'H or 4' x 2' x 4'H. Wild caught Red Tail Boas typically carry parasites and can be much more aggressive than captive bred.īaby and Juvenile Red Tail Boas can be set up in an enclosure as small as a 20 gallon (30" x 12" x 12"H) but within a year will require much larger housing. At Big Apple Pet Supply, we carry only Captive Bred Red Tail Boas to maintain strict quality control. Red Tail Boas typically live a long time and while captive bred Red Tails are docile snakes that adapt to handling well you need to consistently handle your snake to keep it that way. After the second year growth rate slows significantly and an adult size of 6 to 10 feet will take place. By the end of the second year the Red Tail Boa will typically reach 6 to 10 feet total. Red Tail Boas are truly magnificent snakes, but the cute, 3-ounce, 20-inch hatchling will grow to a whopping 4-to-5 feet within a year. Red Tail Boas have been a favorite of snake keepers for many years, but as responsible boa breeders we want to give you all the facts you'll need to make a proper decision on owning these wonderful animals. There are two main types of shielding used in RCA cables: braided shielding and foil shielding. Shielding is a layer of material that surrounds the inner conductor of the cable and helps to prevent signal loss and interference. ShieldingĪnother important factor to consider when choosing RCA cables is the type of shielding used. As a general rule, RCA cables with a gauge between 18 and 24 are suitable for most home audio setups. However, thicker cables are also bulkier and more difficult to work with. Thicker cables have lower resistance and can transmit audio signals with less loss and interference. The gauge of an RCA cable is measured in millimeters, and the thicker the cable, the lower the gauge number. Selecting the Right GaugeĪnother important factor to consider when choosing RCA cables is the gauge, or thickness, of the cables. The best way to determine the ideal length of your RCA cables is to measure the distance between your components and add a little extra to allow for flexibility. However, if your audio components are far apart, you may need longer cables. In general, it's best to use the shortest cables possible to reduce signal loss and interference. When choosing RCA cables, one of the first things to consider is the length of the cables. Some RCA cables may also have additional connectors for video signals or other audio channels. RCA cables consist of a single cable with two connectors on either end: one red connector for the right audio channel and one white or black connector for the left audio channel. RCA cables, named after the Radio Corporation of America that developed them, are a type of interconnect cable that is commonly used in home audio and video systems. When it comes to choosing the right RCA cables for your setup, there are a few key factors to consider. RCA cables, also known as interconnect cables, are used to transmit audio and video signals between components. As an audiophile, the cables you use to connect your audio components are just as important as the components themselves. |
Details
AuthorWrite something about yourself. No need to be fancy, just an overview. ArchivesCategories |